Preheat oven to 325°F. Grease 3 (6-inch) round cake pans, line the bottoms with parchment paper, and grease and flour again. Set aside.*
Combine flour, sugar, cocoa, baking soda, baking powder, and salt in the bowl of a stand mixer fitted with the paddle attachment. Mix on low speed until combined.
In a separate bowl combine sour cream, water, oil, eggs, vanilla, and instant coffee powder. Stir to combine.
With the mixer running on low speed, slowly add the wet ingredients to the dry, scraping the bottom of the bowl as needed.
Evenly divide the batter between prepared pans; bake 35 to 45 minutes or until a toothpick inserted in the center of the cake comes out clean with a few moist crumbs.
Cool in the pans 10 minutes before turning out onto a cooling rack and allowing to cool completely. Wrap in plastive wrap and chill 15 to 30 minutes before frosting.